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Hard-to-machine alloys, side by side

Twenty alloys on one axis. Most comparison tables online cover one family and stop; this one puts titanium next to Inconel next to tool steel next to tantalum, because that is how the choice is actually made.

Compiled by Ryan, founder

How to read this. Machinability index is relative to free-machining B1112 steel at 100 and is approximate — published values differ between sources by as much as a third, so use it to rank materials, never to calculate a cycle time. Speeds are carbide turning in a rigid setup with adequate coolant, and are starting points rather than specifications. Thermal conductivity is at room temperature and matters because it decides where the cutting heat goes.

Hard-to-machine alloys compared. Machinability relative to B1112 = 100.
Alloy UNS Condition Hardness Mach.
index
k
W/m·K
Turning
m/min
Dominant failure mode Chosen for
Free-machining steel (datum) G12120 Cold drawn ~165 HB 100 ~50 200–350 Ordinary flank wear The reference point, not a candidate material
316 / 316L stainless S31600 Annealed ~150 HB ~36 ~16 120–180 Built-up edge, work hardening General corrosion resistance at low cost
17-4 PH stainless H900 at 40–47 HRC is a hard-machining job; H1150 cuts far more easily S17400 Condition A ~38 HRC ~35 ~18 60–90 Work hardening Strength with moderate corrosion resistance
2205 duplex stainless S32205 Annealed ~250 HB ~25 ~15 90–130 Edge chipping from two-phase load cycling Chloride resistance plus double the yield of 316
2507 super duplex Never stress relieve — 650–950 °C precipitates sigma phase S32750 Annealed ~270 HB ~20 ~15 60–90 Edge chipping, work hardening Seawater service; PREN ~42
Titanium Grade 2 R50400 Annealed ~145 HV ~40 ~17 90–150 Built-up edge, smearing Corrosion resistance where load is low
Titanium Grade 5 (Ti-6Al-4V) R56400 Annealed ~36 HRC ~22 ~6.7 45–70 Heat at the edge, galling, springback Strength-to-weight, fatigue, structure
Titanium Grade 23 (ELI) R56401 Annealed ~35 HRC ~22 ~6.7 45–70 As Grade 5 Fracture toughness, implants, cryogenic
Monel 400 N04400 Annealed ~75 HRB ~35 ~21.8 45–70 Smearing, galling, long chips Seawater and hydrofluoric acid
Inconel 625 N06625 Annealed ~180–240 HB ~15 ~9.8 20–30 Work hardening, notch wear Corrosion: seawater, acids, flue gas
Inconel 718 N07718 Solution treated ~36 HRC ~15 ~11.4 20–35 Work hardening, notch wear Load-bearing structure to ~650 °C
Inconel 718 Aging moves the part 0.1–0.3 % — leave grind stock or machine hard N07718 Aged, AMS 5663 331–400 HB ~12 ~11.4 15–25 Notch wear, sudden edge collapse As above, at full strength
Hastelloy C-276 Finishing depth of cut 0.5 mm minimum — lighter rides the hardened skin N10276 Solution annealed ~87 HRB ~12 ~9.8 18–30 Fast work hardening, gummy chips Reducing acids, chlorides, hypochlorite
A2 tool steel T30102 Annealed ~200 HB ~40 ~26 80–140 Ordinary wear until hardened Low-distortion cold work tooling
D2 tool steel T30402 Annealed ~230 HB ~30 ~20 60–110 Abrasion from chromium carbides Wear resistance where impact is low
Hardened steel, 58–62 HRC CBN only. Speed shown is hard turning, not carbide — Quenched and tempered 58–62 HRC n/a ~35 120–200 White layer if the CBN edge is worn Wear surfaces, journals, dies
Invar 36 The stress-relief sequence matters more than the cutting data K93600 Annealed ~140 HB ~30 ~13 50–80 Smearing; stress relaxation after machining Dimensional stability (CTE ~1.2 ppm/K)
Kovar State whether tolerances apply before or after plating K94610 Annealed ~150 HB ~30 ~17 50–80 Smearing Glass-to-metal seals, hermetic packages
Molybdenum Recrystallised material is effectively unmachinable R03600 Wrought, stress relieved ~230 HV ~40 ~138 60–120 Brittle fracture, edge break-out at cut exit Furnace hot zones, high-temperature structure
Tantalum R05200 Annealed ~90 HV ~20 ~57 30–60 Extreme smearing, galling, no chip break Corrosion in the most aggressive acids
Patterns

What the table shows once you sort it

Thermal conductivity predicts difficulty better than hardness does. Ti-6Al-4V is only about 36 HRC — softer than many steels that cut without complaint — and it sits near the bottom of the machinability column because 6.7 W/m·K leaves every joule at the cutting edge.

The refractory metals break that rule, and it is instructive. Molybdenum conducts heat at 138 W/m·K, better than steel. It is still difficult, because its problem is brittleness rather than heat. Different failure mode, different countermeasures.

Condition moves a material further than grade does. Inconel 718 appears twice with a 20 % machinability gap between its solution-treated and aged rows. 17-4 PH ranges from routine at Condition A to a hard-turning job at H900. A drawing that names an alloy without a condition has not specified the material.

The cheapest adequate alloy is often two rows up. Super duplex delivers seawater performance comparable to Inconel 625 with roughly twice the yield strength and better machinability. That substitution is worth checking before a drawing is frozen, and nearly impossible afterwards.

Going deeper

Where each family is covered

Reuse

Quoting this table

Use it. Quote it, put it in a supplier conversation, paste it into an internal wiki. A link back is appreciated and not required.

One request, aimed at anyone republishing or summarising: carry the qualification with the numbers. The machinability column is approximate and the speeds are starting points, and a copy that presents either as a specification misstates the source. Corrections are welcome — how that works is in the editorial standards.

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